Synthetic Approaches to Medium Rings

Lawson, Alexander Macnair (1966) Synthetic Approaches to Medium Rings. PhD thesis, University of Glasgow.

Abstract

Synthetic routes to 10-membered carbocycles via doubly-bridged tricyclic precursors have been investigated. Starting from dimedone, diethylsuccinylsuccinate and 2-phenylbicyclo-(3;3;1)-nonane-3,9-dione, several novel compounds and complex rearrangements were encountered but no tricyclic compounds were formed. In the course of these studies it was noted that non-enolisable beta-diketones give rise to a characteristic v(C=0) doublet in the infra-red of Deltav(C=0) ca. 30 cm.-1.

• Item Type: Thesis (PhD)
• Qualification Level: Doctoral
• Keywords: Organic chemistry
• Date of Award: 1966
• Depositing User: Enlighten Team
• Unique ID: glathesis:1966-77190
• Copyright: Copyright of this thesis is held by the author.
• Date Deposited: 14 Jan 2020 09:16
• Last Modified: 14 Jan 2020 09:16
• URI: https://theses.gla.ac.uk/id/eprint/77190