Structural and Stereochemical Studies in the Diterpenoid Series

Renfrew, Agnes Joyce (1966) Structural and Stereochemical Studies in the Diterpenoid Series. PhD thesis, University of Glasgow.

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Abstract

Part 1. The absolute stereochemistry of the proton at C8 in desoxyrosenono- and rosenono-lactone has never been defined unambiguously, although rosololactone has been shown to possess an 8alpha hydrogen from X-ray analysis of dibromorosololactone. From direct correlation with rosololactone, by way of acetate pyrolysis and with the assistance of gas liquid-mass spectrometric analysis, the proton at C8 in rosenono- and desoxy-rosenono-lactone is assigned an alpha configuration, and hence isorosenono-lactone an 8beta configuration.

Item Type: Thesis (PhD)
Qualification Level: Doctoral
Keywords: Organic chemistry
Date of Award: 1966
Depositing User: Enlighten Team
Unique ID: glathesis:1966-77193
Copyright: Copyright of this thesis is held by the author.
Date Deposited: 14 Jan 2020 09:16
Last Modified: 14 Jan 2020 09:16
URI: http://theses.gla.ac.uk/id/eprint/77193

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