Viscosity Coefficient Measurement and Theoretical Interpretation for Hydrocarbon Mixtures

Young, Kenneth Johnston (1980) Viscosity Coefficient Measurement and Theoretical Interpretation for Hydrocarbon Mixtures. PhD thesis, University of Glasgow.

Abstract

Accurate measurements of viscosity coefficients have been made for liquid hydrocarbon mixtures over a wide range of temperature and pressure. At saturation pressure, specially designed viscometers were used to measure the viscosity coefficient of binary, ternary and quaternary n-alkane mixtures, of binary mixtures of five n-alkane plus benzene systems and of benzene plus cyclohexane from 283 K to 393 K, with an estimated accuracy of +/- 0.5 percent. At elevated pressures, a falling-body viscometer with self-centring sinker was used to measure the viscosity coefficient of n-hexane, n-hexadecane and four binary mixtures with an estimated accuracy of +/- 3 percent from 298 K to 373 K at pressures up to 500 MPa or the freezing pressure. To overcome certain weaknesses in design of this instrument, a new viscometer was designed, built and tested. The accuracy of density measurement under elevated pressure was also significantly improved.

• Item Type: Thesis (PhD)
• Qualification Level: Doctoral
• Keywords: Physical chemistry
• Date of Award: 1980
• Depositing User: Enlighten Team
• Unique ID: glathesis:1980-77161
• Copyright: Copyright of this thesis is held by the author.
• Date Deposited: 14 Jan 2020 09:18
• Last Modified: 14 Jan 2020 09:18
• URI: http://theses.gla.ac.uk/id/eprint/77161