Preparation, Redox and Substitution Reactions of Solvated Metal Ions in Non Aqueous Media

Cameron, James Hay (1980) Preparation, Redox and Substitution Reactions of Solvated Metal Ions in Non Aqueous Media. PhD thesis, University of Glasgow.

Abstract

Solvated iron(II), in MeCN solution, is prepared by oxidation of iron metal with WF6 , NOPF6 and PF5 or by fluoride ion transfer from FeF2 to PF5 or AsF5. Fe(NCMe)6 3+ is not produced from oxidation of iron metal, fluoride ion transfer from FeF3 or oxidation of Fe(NCMe)6 2+. Fe(NCMe)6 2+ is oxidised, by Cl2 producing FeCl4-. A ligand is necessary to stabilise Fe(lll) in MeCN.

• Item Type: Thesis (PhD)
• Qualification Level: Doctoral
• Keywords: Inorganic chemistry
• Date of Award: 1980
• Depositing User: Enlighten Team
• Unique ID: glathesis:1980-77234
• Copyright: Copyright of this thesis is held by the author.
• Date Deposited: 14 Jan 2020 09:15
• Last Modified: 14 Jan 2020 09:15
• URI: https://theses.gla.ac.uk/id/eprint/77234