The Crystal and Molecular Structure of Some Organic Polysulphides

Dawson, Ian MacPhail (1948) The Crystal and Molecular Structure of Some Organic Polysulphides. PhD thesis, University of Glasgow.

Abstract

In the investigation of the structure of some organic polysulphides an account is given of unit cell and space group measurements for diphenyl disulphide, di-p-tolyl disulphide, and beta,beta'-diiododiethyl trisulphide. Preliminary structure analysis by the method of Patterson synthesis is reported in the case of di-p-tolyl disulphide, followed by the results of the complete analysis of the beta,beta'-diiododi ethyl trisulphide structure, A chain-like structure has been established for the molecule I. CH2.CH2.S.S.S.CH2.CH2.I. A sulphur-sulphur bond length of 2.04t .04 A and an S-S-S bond angle of 113

• Item Type: Thesis (PhD)
• Qualification Level: Doctoral
• Keywords: Organic chemistry, Molecular chemistry, Biochemistry
• Date of Award: 1948
• Depositing User: Enlighten Team
• Unique ID: glathesis:1948-79690
• Copyright: Copyright of this thesis is held by the author.
• Date Deposited: 04 Mar 2020 15:28
• Last Modified: 04 Mar 2020 15:28
• URI: https://theses.gla.ac.uk/id/eprint/79690