The Crystal and Molecular Structure of Some Organic Polysulphides

Dawson, Ian MacPhail (1948) The Crystal and Molecular Structure of Some Organic Polysulphides. PhD thesis, University of Glasgow.

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Abstract

In the investigation of the structure of some organic polysulphides an account is given of unit cell and space group measurements for diphenyl disulphide, di-p-tolyl disulphide, and beta,beta'-diiododiethyl trisulphide. Preliminary structure analysis by the method of Patterson synthesis is reported in the case of di-p-tolyl disulphide, followed by the results of the complete analysis of the beta,beta'-diiododi ethyl trisulphide structure, A chain-like structure has been established for the molecule I. CH2.CH2.S.S.S.CH2.CH2.I. A sulphur-sulphur bond length of 2.04t .04 A and an S-S-S bond angle of 113

Item Type: Thesis (PhD)
Qualification Level: Doctoral
Keywords: Organic chemistry, Molecular chemistry, Biochemistry
Date of Award: 1948
Depositing User: Enlighten Team
Unique ID: glathesis:1948-79690
Copyright: Copyright of this thesis is held by the author.
Date Deposited: 04 Mar 2020 15:28
Last Modified: 04 Mar 2020 15:28
URI: http://theses.gla.ac.uk/id/eprint/79690

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