Topics in the Chemistry of Niobium and Tantalum Pentafluorides and Other Higher Halides

Fuggle, John C (1971) Topics in the Chemistry of Niobium and Tantalum Pentafluorides and Other Higher Halides. PhD thesis, University of Glasgow.

Full text available as:
[img]
Preview
PDF
Download (8MB) | Preview

Abstract

Research presented in this thesis falls into four areas. 1) Vibrational spectra of pentafluorides. 2) Preparation and spectra of NbF5 and TaF5 complexed with Lewis bases. 3) Preparation and some properties of some Nb, and Ta (V) fluoride-halides and pseudohalides. 4) 93Nb n.q.r. spectra of some compounds derived from 93Nb n.q.r. spectra of NbF5 and vibrational soectra of NbF5 and TaF5 are interpreted in terms of a very small deviation from C4v symmetry in the tetrameric molecules of the solid state. I.R. spectra suggest that NbF5, and TaF5 are polymeric in the liquid state up to at least 150

Item Type: Thesis (PhD)
Qualification Level: Doctoral
Keywords: Inorganic chemistry, Physical chemistry
Date of Award: 1971
Depositing User: Enlighten Team
Unique ID: glathesis:1971-78587
Copyright: Copyright of this thesis is held by the author.
Date Deposited: 30 Jan 2020 15:09
Last Modified: 30 Jan 2020 15:09
URI: http://theses.gla.ac.uk/id/eprint/78587

Actions (login required)

View Item View Item

Downloads

Downloads per month over past year