Synthetic and Mechanistic Investigations of Organoplatinum Chemistry

Phillips, Ian G (1981) Synthetic and Mechanistic Investigations of Organoplatinum Chemistry. PhD thesis, University of Glasgow.

Abstract

The addition of PMe2Ph to [ Pt2Cl4(PMe2Ph)2] at low temperatures produces the ions [PtCl (PMe2Ph)3]+ and [PtCl3(PMe3Ph)]- as major products, as well as some of the expected [PtCl2(PMe2Ph)2]. Less ionic material is produced from the addition of PBu3 to [Pt2Cl4(PMe2Ph)2] and PMe2Ph to [Pt2Cl4(PBu3)3] , and none at all from the addition of PBu3 to [Pt2Cl4(PBu3)2] . Ionic materials are also produced in the reactions of PMePh2 and SPMePh2 with [Pt2Cl4(PBu3)2] , and of PBu3 and SPBu3 with [Pt2Cl4(PMePh2)2]. The nature of the neutral ligands involved has a profound effect on the course of the reactions.

• Item Type: Thesis (PhD)
• Qualification Level: Doctoral
• Keywords: Physical chemistry, Inorganic chemistry, Organic chemistry
• Date of Award: 1981
• Depositing User: Enlighten Team
• Unique ID: glathesis:1981-77168
• Copyright: Copyright of this thesis is held by the author.
• Date Deposited: 14 Jan 2020 09:17
• Last Modified: 14 Jan 2020 09:17
• URI: https://theses.gla.ac.uk/id/eprint/77168